And Selected Reviews








460      Living ROMP Synthesis and Redox Properties of Diblock Ferrocene/Cobalticenium Copolymers.

R. Ciganda, H. Gu, P. Castel, P. Zhao, J. Ruiz, R. Hernández, D. Astruc, Macromol. Rapid Commun. 2016, 37, 105-111. DOI: 10.1002/marc.201500566.


461      Gold Nanoparticles as Sensors in Colorimetric and Fluorescence Detection of Chemical Warfare Agents
P. Zhao, X. Lai, G. Yue, S. Su, N. Li,  D. Astruc,  M. Shuai, Coord. Chem. Rev. 2016, 311, 75-84

462      Introduction to Nanomedicine. Editorial.

D. Astruc, Molecules 2016, 21, 4; doi: 10.3390/molecules2101000


463      Pd/C as an efficient and reusable catalyst for the selective  N-alkylation of amines with alcohols

X. Liu, P. Hermange, J. Ruiz, D. Astruc. ChemCatChem, 2016, March 18, 2016. Volume 8, Issue 6 (pages 1043–1045) DOI: 10.1002/cctc.201501346R1


464      Highly efficient transition metal nanoparticle catalysts in aqueous solutions.

C. Wang, R. Ciganda,  L. Salmon, D. Gregurec, J. Irigoyen, S. Moya, J. Ruiz, D. Astruc. Angew. Chem. Int. Ed. 2016, 55, 3091-3095. DOI: 10.1002/anie.201511305


465      Diblock Polyelectrolytic Copolymers Containing Cationic Iron and Cobalt Sandwich Complexes: Living ROMP Synthesis and Redox Properties.

H. Gu, R. Ciganda, P. Castel, P. Zhao, J. Ruiz, R. Hernández, D. Astruc. Macromol. Rapid Commun. 2016, 37, 630-636. DOI : 10.1002/marc.201500679


466      Diblock Metallocopolymers Containing Various Iron Sandwich Complexes: Living ROMP Synthesis and Selective Reversible Oxidation.

H. Gu, R. Ciganda, R. Hernández, P. Castel, A. Vax, P. Zhao, J. Ruiz, D. Astruc. Polym. Chem. 2016, 7, 2358-2371. DOI: 10.1039/C6PY00202A


467      Metal-Catalyzed Azide-Alkyne “Click” Reactions: Mechanistic Overview and Recent Trends.

Changlong Wang, Djamila Ikhlef, Samia Kahlal, Jean-Yves Saillard, Didier Astruc. Coord. Chem. Rev. 2016, 316, 1-20. DOI: 10.1016/j.ccr.2016.02.010


468      Molecular Sieving with Vertically Aligned Mesoporous Silica Films and E lectronic Wiring through Isolating Nanochannels.

N. Vilà, E. André, R. Ciganda, J. Ruiz, D. Astruc, A. Walcarius, Chem. Mater. 2016, 28, 2511-2514. DOI: 10.102/acs.chemmater.6b00716


469      On Metallocene-containing Macromolecules and their Applications

H. Gu, R. Ciganga, S. Gatard, F. Lu, P. Zhao, J. Ruiz, D. Astruc, J. Organomet. Chem. 2016, 813, 95-102.


470      From Mono-to Tris-1,2,3-triazole-Stabilized Gold Nanoparticles and their Compared Catalytic Efficiency in 4-Nitrophenol Reduction

C. Wang, L. Salmon, Q. Li, M. Igartua, S. Moya, R. Ciganda, J. Ruiz, D. Astruc. Inorg. Chem. 2016, DOI 10.1021/acs.inorgchem.6b01092


471    Living ROMP Syntheses and Redox Properties of Triblock Metallocopolymer Redox Cascades.

H. Gu, R. Ciganda, P. Castel, J. Ruiz, D. Astruc. Macromolecules201649 (13), pp 4763–4773 DOI: 10.1021/acs.macromol.6b01046


472    Liquid-Liquid Interfacial Electron Transfer from Ferrocene to Au(III): An Ultra-Simple and Fast Au Nanoparticle Synthesis in  Water Under Ambient Conditions.            

R. Ciganda, J. Irigoyen, D. Gregurec, R. Hernández, S. Moya, C. Wang, J. Ruiz, D. Astruc, Inorg. Chem. 2016, 55 (13), pp 6361–6363


473    Design and applications of an efficient amphiphilic “click” CuI catalyst in water.

C. Wang, D. Wang, S. Yu, T. Cornilleau, J. Ruiz, L. Salmon, D. Astruc. ACS Catal. 2016, 6, 5424−5431.


274    Supramolecular Nanoreactors for Catalysis.

C. Deraedt, D. Astruc. Coord. Chem. Rev. 2016, 324, 106-122. DOI: 10.1016/j.ccr.2016.07.007


475    The Dual Functional Epoxy Material with Automatic Damage Indication and Self

Y. K. Guo, L. Chen, D. G. Xu, J. R. Zhong, G. Z. Yue, D. Astruc, M. B. Shuai, P. X. Zhao
R S C Adv. 2016, 6, 65067-65071. DOI: 10.1039/C6RA13519F.


476    Base-catalyzed hydrogen-deuterium exchange and dehalogenation reactions of
1,2,3-triazole derivatives

D. Wang, S. Chen, J. Wang, D. Astruc, B. Chen., Tetrahedron, 2016, 72, 6375-6379.


477    Precise Localization of Metal Nanoparticles in Dendrimer Nanosnakes or Inner
Periphery and Consequences in Catalysis

X. Liu, D. Gregurec, J. Irigoyen, A. Martinez, S. Moya, R. Ciganda, P. Hermange, J. Ruiz, D.
Astruc, Nat. Commun.vol. 7,‎ 2016, (DOI 10.1038/ncomms13152)


478   Why is Ferrocene so Exceptional?.

D. Astruc. Eur. J. Inorg. Chem., 2016, 000. DOI: 10.1002/ejic.201600983




439      Efficient and Magnetically Recoverable “Click” PEGylated γ-Fe2O3-Pd Nanoparticle Catalysts for Suzuki-Miyaura, Sonogashira, and Heck Reactions with Positive Dendritic Effects

D. Wang, C. Deraedt, L. Salmon, C. Labrugère, L. Etienne, J. Ruiz, D. Astruc, Chem. Eur. J. 2015, 21, 1508-1519. DOI: 10.1002/chem.201404590


440      Robust, efficient and recyclable catalyst by impregnation of dendritically preformed Pd nanoparticles on magnetic support.

C. Deraedt, D. Wang, L. Salmon, L. Etienne, C. Labrugère, J. Ruiz, D. Astruc, ChemCatChem 2015, 7, 303-308. DOI: 10.1002/cctc.201402775.


441      Gold Nanosweepers (AuNSs): A Novel Application of PEGylated AuNPs.

G. Yang, N. Li, H.-Y. Chow, H. Zhang, J. Ruiz, X. Lai, D. Astruc, K.-Y. Wong, P. Zhao, Chem. Letters 2015, 44, 191-193. DOI 10.1246/cl.140964.


442      The Redox Functions of Metallodendrimers.

D. Astruc, J. Ruiz, J. Inorg. Organomet. Polym. Mater.  2015, 25, 2-11. DOI: 10.1007/s10904-014-0091-3 (H. W. Neuse issue).


443      Organoiron-mediated synthesis and redox activity of organoiron-containing dendrimers.

D. Astruc, Y. Wang, A. Rapakousiou, A. Diallo, R. Djeda, J. Ruiz, C. Ornelas, Polyhedron 2015, 86, 24-30 (C. Lapinte issue),         


444      Basic Concepts and Recent Advances in Nitrophenol Reduction by Gold- and Other Transition Metal Nanoparticles.

P. Zhao, X. Feng, D. Huang, G. Yang,  D. Astruc, Coord. Chem. Rev. 2015, 287, 114-136.


445      Synthesis and Redox Activity of “Clicked” Triazolylbiferrocenyl Polymers, Network Encapsulation of Gold and Silver Nanoparticles and Anion Sensing.

A. Rapakousiou, C. Deraedt, J. Irigoyen, Y. Wang, N. Pinaud, L. Salmon, J. Ruiz, S. Moya, J. Ruiz, D. Astruc, Inorg. Chem. 2015, 54, 2284–2299. DOI: 10.1021/ic5028916.


446      Alkynyl-functionalized imidazolium for “click” dendrimer functionalization and palladium nanoparticle stabilization.

C. Deraedt, M. d’Halluin, S. Lesturgez, L. Salmon, G. Goglio, J. Ruiz, D. Astruc, Eur. J. Inorg. Chem. 2015, 27, 1345-1350. DOI: 10.1002/ejic.201403045


447      Catalytically-Active Palladium Nanoparticles Stabilized by Triazolylbiferrocenyl-Containing Polymers.

C. Deraedt, A. Rapakousiou, H. Gu, L. Salmon, J. Ruiz, D. Astruc,J. Inorg. Organomet. Polym. Mater. 2015, 25, DOI: 10.1007/s10904-014-0161-6 (H. W. Neuse issue).


448      Sodium Hydroxide-Catalyzed Transfer Hydrogenation of Carbonyl Compounds and Nitroarenes Using Ethanol or Isopropanol as Both Solvent and Hydrogen Donor.

D. Wang, C. Deraedt, J. Ruiz, D. Astruc, J. Mol. Cat. A 2015, 400, 14–21. doi:10.1016/j.molcata.2015.01.024.


449      On the Redox Chemistry of Ferrocenes and Other Iron Sandwich Complexes and its Applications.

D. Astruc, J. Ruiz, J. Inorg. Organomet. Polym. Mater. 2015, 25, DOI 10.1007/s10904-015-0178-5 (H. W. Neuse issue).


450      A Tris(triazolate) Ligand for a Highly Active and Magnetically Recoverable Palladium Catalyst of Selective Alcohol Oxidation Using Air at Atmospheric Pressure,

D. Wang, C. Deraedt, L. Salmon, C. Labrugère, L. Etienne, J. Ruiz, D. Astruc, Chem. Eur. J. 2015, 21, DOI: 10.1002/chem.201500122.


451      New Polysilyl Dendritic Precursors of Triazolylferrocenyl and Triazolylcobalticenium Dendrimers, Comparative Electrochemical Study and Stabilization of Small Catalytically-Active Pd Nanoparticles.

S. Gatard, C. Deraedt, A. Rapakousiou, D. Sonet, L. Salmon, J. Ruiz, D. Astruc, Organometallics 2015, 34, 1643-1650. DOI:10.1021/acs.organomet.5b00035.   


452      Click Metallodendrimers and their Functions.

D. Astruc, R. Ciganda, C. Deraedt, S. Gatard, L. Liang, N. Li, C. Ornelas, A. Rapakousiou, J. Ruiz, D. Wang, Y. Wang, P. Zhao, Synlett 2015, 26, 1437-1449. DOI 10.1055/s-0034-1380699.


453      Catalysis Inside Dendrimers.

Didier Astruc, D. Wang, C Deraedt, L. Liang, R. Ciganda, J. Ruiz, Synthesis 2015, 47,  2017-2031 DOI: 10.1055/s-0034-1380868.


454      The Golden Age of Transfer Hydrogenation.

D. Wang, D. Astruc, Chem. Rev. 2015, 115, 6621-6686. DOI 10.1021/acs.chemrev.5b00203.


455     Magnetic and Dendritic Catalysts.

D. Wang, C. Deraedt, J. Ruiz, D. Astruc, Acc Chem. Res. 2015, 48, 1871-1880. DOI: 10.1021/acs.accounts.5b00039.


456      ROMP Synthesis and Redox Properties of Polycationic Metallopolymers Containing the Electron-Reservoir Complex [Fe(η5-C5H5)(η6-C6Me6)][PF6].

H. Gu, R. Ciganda, R. Hernández, P. Castel, P. Zhao, J. Ruiz, Macromolecules 2015, 48 (7) 6071-6076, ,


457      Robust Pentamethylferrocene Polymers and Supramolecular Polymers and Controlled Self-Assembly of Pentamethylferricenium Polymer-Embedded Ag, AgI and Au Nanoparticles.

H. Gu, R. Ciganda, P. Castel, A. Vax, D. Gregurec, J. Irigoyen, S. Moya, L. Salmon, P. Zhao, J. Ruiz, R. Hernández, D. Astruc. Chem. Eur. J. 2015, 21, 18177-18186.

458      Reaction Mechanisms of Transition-Metal-Catalyzed Azide-Alkyne Cycloaddition "Click" Reactions: A DFT Investigation

D. Ikhlef, C. Wang, S. Kahlal, B. Maouche, D. Astruc, J.-Y. Saillard, Computational and Theoretical Chemistry, 2015, 1073, 131-138.


459      Catalytically Active Palladium Nanoparticle-Cored Ferrocenyl-Terminated Dendrimers

F. Lu, D. Astruc? Eur. J. Inorg. Chem. 2015, 5595-5600. DOI:10.1002/ejic.201501103.




408   The multiple shapes of anisotropic gold nanoparticles: synthesis, properties, applications and toxicity.

N. Li, P. Zhao, D. Astruc, Angew. Chem., Int. Ed. 2014, 52, 1756–1789. DOI:


409      “Click” synthesis and redox activity of a water-soluble triazolylcobalticinium polyelectrolyte.

A Rapakousiou, Y. Wang, J. Ruiz, D. Astruc, J. Inorg. Organomet. Polym. Mater. 2014, 24 (1), 107-113 (Dwight Sweigart issue). DOI 10.1007/s10904-013-9958-y.


410       “Homeopathic” Palladium Nanoparticle Catalysis of Cross Carbon–Carbon Coupling Reactions.

C. Deraedt, D. Astruc? Acc. Chem. Res. 2014, 47, 494-503. DOI: 10.1021/ar400168s


411      A highly active and magnetically recoverabletris(triazolyl) Cu(I) catalyst for “click” alkyneazide cycloaddition reactions.

D. Wang, L. Etienne, M. E. Igartua, S. Moya, D. Astruc? Chem. Eur. J. 2014, 20, 4047-4054. (DOI: 10.1002/chem.201304536)


412      Rhodicenium Salts from Basic Chemistry to Polyelectrolyte and Dendritic Macromolecules.

A. Rapakousiou, L. H. Jimenez, Y. Wang, C. Mouche, D. Astruc, Organometallics, 2014, 33, 1259–1265 (


413     Metallodendrimers in Three Oxidation States with Electronically Interacting Metals and Stabilization of Size-Selected Gold Nanoparticles.

Y. Wang, L. Salmon, J. Ruiz, D. Astruc, Nature Communications 2014,5, number 3489; doi: 10.1038/ncomms4489 (2014)


414      Gold Nanoparticles Stabilized by Glycodendrimers: Synthesis and Application to the Catalytic Reduction of 4-Nitrophenol.

S. Gatard, L. Salmon, C. Deraedt, J. Ruiz, D. Astruc,  S. Bouquillon, Eur. J. Inorg. Chem. 2014, 2671-2677, DOI: 10.1002/ejic.201402067R1


415      Uncatalyzed Hydroamination of Electrophilic Organometallic Alkynes: Fundamental, Theoretical and Applied Aspects.

Y. Wang, C. Latouche, A. Rapakousiou, C. Lopez, I. Ledoux-Rak, J. Ruiz, J.-Y. Saillard, D. Astruc, Chem. Eur. J.2014, 20, 8076-8088, DOI: 10.1002/chem.201400373


416      “Click” Chemistry Mildly Stabilizes Bifunctional Gold Nanoparticles for Sensing and Catalysis.

N. Li, P. Zhao,N. Liu,M. E. Igartua,S. Moya,L. Salmon,J. Ruiz, D. Astruc, Chem. Eur. J. 2014, 20, 8363-8369, DOI: 10.1002/chem.201402652


417     Ruthenium Catalysts in Organic Synthesis.

D. Wang, D. Astruc, Molecules 2014, 19, 4635-4653.(doi:10.3390/molecules19044635)(Ru Dragutan issue)


418      “Click” Dendrimer-stabilized Pd Nanoparticles as a Green Catalyst for Efficient C-C Cross-coupling Reactions and Reduction of 4-Nitrophenol.

C. Deraedt, L. Salmon, D. Astruc, Adv. Syn. Catal. 2014, 356, 2525-2538. DOI 10.1002/adsc. 201400153.


419      Catalysis by 1,2,3-Triazole- and Related Transition-Metal Complexes.

D. Huang, P. Zhao, D. Astruc, Coord. Chem. Rev. 2014, 272, 145-165, DOI: 10.1016/j.ccr.2014.04.006.


420      Multi-function Redox Polymers: Electrochrome, Polyelectrolyte, Sensor, Electrode Modifier, Nanoparticle Stabilizer and Catalyst Template.

C. Deraedt, A.Rapakousiou, Y. Wang, L. Salmon, M. Bousquet, D. Astruc, Angew. Chem., Int. Ed. 2014, 53, 8445-8449 DOI: 10.1002/anie.201403062


421      Metallation of Polyamine Dendrimers with Ethynylcobalticenium for the Construction of Mono- and Heterobimetallic Polycationic Metallodendrimers.

Y. Wang, A. Rapakousiou, J. Ruiz, D. Astruc, Chem. Eur. J. 2014, 20 (35):11176-11186. DOI: 10.1002/chem.201403085


422      Fast-growing Field of Magnetically Recyclable Nanocatalysts.

D. Wang, D. Astruc, Chem. Rev. 2014, 114, 6949-6985. DOI: 10.1021/cr500134h


423      Mixed-valent metallodendrimers: design and functions.

D. Astruc, A. Rapakousiou, Y. Wang, R. Djeda, A. Diallo, J. Ruiz, C. Ornelas, J. Coord. Chem. 2014, 67, 3809-3821. DOI 10.1080/00958972.2014.939648 (Juan Costamagna issue).


424      Click Synthesis of Nona-PEG-branched Triazole Dendrimers and Stabilization of Gold Nanoparticles that Efficiently Catalyze p-Nitrophenol reduction.

N. Li, M. Echeverria, S. Moya, J. Ruiz, D. Astruc. Inorg. Chem. 2014, 53, 6954-5961;


425      ROMP Synthesis of Cobalticenium-EnaminePolyelectrolytes.

Y. Wang, A. Rapakousiou, D. Astruc, Macromolecules 2014, 47, 3767-3774,  DOI 10.1021/ma5007864.


426      Olefin Metathesis From Historical Account to Recent Trends.

D. Astruc, In Olefin Metathesis. Theory and Practice, Grela, K. Ed. Wiley, Hoboken, N. J., 2014, pp. 5-30.


427      Click Chemistry of an Ethynylarene Iron Complex. Syntheses, Properties and Redox Chemistry of Cationic Bimetallic and Dendritic Iron-Sandwich Complexes.

A. Rapakousiou, Y. Wang, R. Ciganda, J.-M. Lasnier, D. Astruc, Organometallics 2014, 33, 3583-3590. DOI: 10.1021/om500495r

428      Nanogold plasmonic photocatalysis for organic synthesis and clean energy conversion.

C. Wang, D. Astruc, Chem. Soc. Rev. 2014, 43 (20), 7188-7216. DOI: 10.1039/c4cs00145a.


429      Palladium Nanoparticles Stabilized by Glycodendrimers and their Application in Catalysis.

S. Gatard, L. Salmon, C. Deraedt, J. Ruiz, D. Astruc, S. Bouquillon, Eur J. Inorg. Chem.2014, 26, 4369-4375. DOI: 10.1002/ejic.201402457.


430      Gold nanoparticles as electron reservoir redox catalysts for the 4-nitrophenol reduction: strong stereoelectronic ligand influence.

R. Ciganda, N. Li, C. Deraedt, S. Gatard, P. Zhao, L. Salmon, R. Hernandez, J. Ruiz, D. Astruc, Chem. Commun. 2014, 50, 10126-10129. DOI : 10.1039/C4CC04454A


431      Living Ring-Opening Metathesis Polymerization and Redox-Sensing Properties of Norbornene Polymers and Copolymers Containing Ferrocenyl and Tetraethylene Glycol Groups.

H. Gu, A. Rapakousiou, P. Castel, N. Guidolin, N. Pinaud, J. Ruiz, D. Astruc, Organometallics, 2014, 33 (16), 4323–4335


432      Recyclable Catalytic Dendrimer Nanoreactor for Part-Per-Million CuI Catalysis of “Click” Chemistry in Water.

C. Deraedt, N. Pinaud, D. Astruc, J. Am. Chem. Soc. 2014,136 (34), 12092–12098.


433      The Redox Functions of Metallodendrimers.

D. Astruc, J. Ruiz, J. Inorg. Organomet. Chem. 2014, DOI: 10.1007/s10904-014-0091-3


434      Sodium borohydride stabilizes very efficient gold nanoparticle catalyst.

C. Deraedt, L. Salmon, S. Gatard, R. Ciganda, R. Hernandez, J. Ruiz, D. Astruc. Chem. Commun. 2014, 50, 14194-14196. DOI :10.1039/C4CC05946H


435      Mixed-Valent Intertwinned Polymer Units Containing Biferrocenium Chloride Side Chains Form Nanosnakes that Encapsulate Gold Nanoparticles.

A. Rapakousiou, C. Deraedt, H. Gu, L. Salmon, C. Belin, J. Ruiz, D. Astruc. J. Am. Chem. Soc. 2014, 136, 13995-13998.


436      Stabilization of AuNPs by Monofunctional Triazole Linked to Ferrocene, Ferricenium or Coumarin and Applications to Synthesis, Sensing and Catalysis.

N. Li,  P. Zhao, M. E. Igartua, A. Rapakousiou, L. Salmon, S. Moya, J. Ruiz,  D. Astruc, Inorg. Chem. 2014, 53 (21), 11802–11808. DOI: 10.1021/ic5021498.


437      “Click” Assemblies and Redox Properties of Arene- and Gold-nanoparticle-cored Triazolylbiferrocene-terminated Dendrimers".

A. Rapakousiou, R. Djeda, M. Grillaud, N. Li, J. Ruiz, D. Astruc, Organometallics 2014, 33, 6953-6962.


438      Tunneling Dendrimers. Enhancing charge transport through insulating layer using redox molecular objects
S. Lhenry, J. Jalkh, Y.  Leroux, J. Ruiz, R. Ciganda, D. Astruc, P. Hapiot, J. Am. Chem. Soc. 2014, 136, 17950-17953. DOI 10.1021/ja5110359




389. Catalysis by Dendrimer-Stabilized and Dendrimer-Encapsulated Late-Transition-Metal Nanoparticles

D. Astruc, A. K. Diallo, C. Ornelas. In Nanomaterials and Catalysis, Eds. P. Serp, K. Philippot, Wiley-VCH, 2013, Chap. 3, pp. 101-127.


390. State of the Art in the Synthesis of Gold Nanoparticles

P. Zhao, N. Li, D. Astruc. Coord. Chem. Rev., 2013, 257, 638-665.


391 The Clicked Pyridyl-Triazole Ligand : From Homogeneous to Robust, Reclyclable Heterogeneous Mono- and Polymetallic Palladium catalysts for Efficient Suzuki-Miyaura, Sonogashira, anf Heck reactions.

D. Wang, D. Denux, J. Ruiz, D. Astruc. Adv. Syn. Catal. 2013, 355, 129-142.


392 Dendritic Molecular Nanobatteries and the Contribution of Click Chemistry

D. Astruc, P. Zhao, L. Liang, A. Rapakousiou, R. Djeda, A. K. Diallo, T. Kusamoto, J. Ruiz, C. Ornelas. J. Inorg. Organomet. Chem. Polym. Mater . 2013, 23, 41-49 (Hiroshi Nishihara issue).


393 Organometalic Dendrimers : Design, Redox Properties and Catalytic Function

D. Astruc, C. Ornelas, J. Ruiz, In Complexity in Chemistry and Beyond : Interplay and Experiment. Eds. : C. L. Hill, D. G. Musaev. Springer, Dordrecht, 2013.


394 How a simple clicked” PEGylated 1,2,3-triazole ligand stablilizes gold nanoparticles for multiple usage.

P. Zha o , N. Li, L. Salmon, N. Liu, J. Ruiz, D. Astruc. Chem. Commun. 2013, 49, 3218-3220.


395 Synthesis, Redox Activity of Rigid Ferrocenyl Dendrimers and Isolation of Robust Ferricinium and Class-II Mixe Valence Dendrimers.

A. K. Diallo, J. Ruiz, D. Astruc. Chem. Eur. J . 2013, 54, 8913-8921.


396 Dendritic catalysis – Basic concepts and recent trends

D. Wang, D. Astruc. Coord. Chem. Rev . 2013, 257, 2317-2334.


397. Mild Uncatalyzed Hydroamination of an Electrophilic Alkyne, Ethynylcobalticinium.

Y. Wang, A. Rapakousiou, C. Latouche, J.-C. Daran, A. Singh, I. Ledoux-Rak, J. Ruiz, J.-Y. Saillard, D. Astruc. Chem. Commun . 2013 , 49 (52), 5862 - 5864


398 Synthesis and in-vitro studies of gold nanoparticles loaded with docetaxel

R. Oliveira, P. Zhao, N. Li, L. C de Santa Maria, J. Vergnaud-Gauduchon, J. Ruiz; D. Astruc, G. Barratt

Internat. J. Pharmaceutics, 2013, 454, 703-711.

399 Click’ Synthesis and Redox Properties of Triazolyl Cobalticinium Dendrimers.

A. Rapakousiou, Y. Wang, C. Belin, N. Pinaud, J. Ruiz, D. Astruc. Inorg. Chem . 2013, 52, 6685-6693.


400 A recyclable ruthenium( II ) complex supported on magnetic nanoparticles: a regioselective catalyst for alkyne–azide cycloaddition

D. Wang, L. Salmon, J. Ruiz , D. Astruc. Chem. Commun . 2013 , 49, 6956-6958.


401 The metathesis reactions: recent trends and new challenges

C. Deraedt, M. d’Halluin, D. Astruc. Eur. J. Inorg. Chem . 2013, 4881-4908.


402Chimie Organométallique et Catalyse

D. Astruc. EDP Sciences, Les Ullis , 2013, 660 pp


403 “Click” dendrimers as efficient nanoreactors in aqueous solvent: Pd nanoparticles stabilization for sub-ppm Pd catalysis of Suzuki-Miyaura reactions of aryl bromides.

C. Deraedt, L. Salmon, L. Etienne, J. Ruiz, D. Astruc, Chem. Commun . 2013 , 49, 8169-8171


404. Ferrocenyl Dendrimers with Ionic Tethers and Dendrons

A. Rapakousiou, Y. Wang, F. Nzulu, R. Djeda, N. Pinaud, J. Ruiz, D. Astruc. Organometallics . 2013, 32, 3679-3690 (special ferrocene issue)


405. “Click” Star-Shaped and Dendritic PEGylated Gold Nanoparticle-Carborane Assemblies.

Na Li , P. Zhao, L. Salmon, J. Ruiz, M. Zabawa, N. S. Hosmane, D. Astruc. Inorg. Chem. 2013 , 52, 11146-11155.


406. Poly(Biferrocenylethynyl)arene and Bis(biferrocenyl)diynyl Complexes and their Redox Chemistry

Y. Wang, A. Rapakousiou, G. Chastanet, L. Salmon, J. Ruiz, D. Astruc. Organometallics 2013 , 32, 6136-6146.


407 Efficient Click-Polymer-Stabilized Palladium Nanoparticle Catalysts for Suzuki- Miyaura Reactions of Bromoarenes and Reduction of 4-Nitrophenol in Aqueous Solvents.

Deraedt, L. Salmon, J. Ruiz, D. Astruc, Adv. Synth. Catal . 2013, 355, 2992-3001




377. Application of gold nanoparticles to the diagnostic and therapy of cancer.

A. Llevot, D. Astruc. Chem. Soc. Rev. 2012, 41, 242-257.


378. Nanoscience makes catalysis greener.

V. Polshettiwar,] J.-M. Basset, and D. Astruc. ChemSusChem 2012, 5, 6-8.


379. Visible-Light Generation of the Naked 12-Electron Fragment C5H5Fe+: Alkyne-to-Vinylidene Isomerization and Synthesis of Polynuclear† Iron Vinylidene and Alkynyl Complexes Including Hexairon Stars.

Y. Wang, A. K.Diallo, C. Ornelas, J. Ruiz, D. Astruc. Inorg. Chem . 2012, 51 , 119-127.


380 . Click Dendrimers and Triazole-Related Aspects: Catalysts, Mechanism, Synthesis, and Functions. A Bridge between Dendritic Architectures and Nanomaterials.

D. Astruc, L. Liang, A. Rapakousiou, J. Ruiz . Acc. Chem. Res . 2012, 45, 630-640. ASAP DOI: 10.1021/ar200235m


381. Click Functionalization of Gold Nanoparticles Using the Very Efficient Catalyst C opper I (Hexabenzyl) T ris-(2- a minoethyl) Amine Bromide.

P. Zhao, M. G rillaud , L. Salmon, J. Ruiz, D. Astruc . Adv. Syn. Catal . 2012, 354, 1001-1011.


382. "Robust Assembly of Dendrimers as Active Redox Sensing Monolayer. Example of Oxo-anion Sensing."

Y. R. Leroux, F. Hui, J. Ruiz, D. Astruc,  Philippe Hapiot. Chemistry - A European Journal. Volume 18, Issue 23; pages 7041–7044, 2012. DOI: 10.1002/chem.201200172


383. Docetaxel nanotechnology in anti-cancer therapy

P. Zhao, D. Astruc. ChemMedChem 2012, 7, DOI : 10.1002/cmdc.201200052


384. Electron-Transfer Processes in Dendrimers and their Implication in Biology, Catalysis, Sensing and Nanotechnology

D. Astruc. Nature Chemistry, 2012, 4, 255-267 (Open access), DOI:10.1038/nchem.1304


385. Catalysis in aqueous solvent of cross C-C coupling reactions by Bis- and Tris(ferrocenyltriazolylmethyl)arene-stabilized Pd(0) nanoparticles

L. Liang, A. K. Diallo, L. Salmon, J. Ruiz, D. Astruc. Eur. J. Inorg. Chem. 2012, DOI: 10.1002/ejic.201200098


386. Detection of molecular spin-state change in ultrathin films by photonic methods.

I. Gural ’ skiy, C. Quintero, K. Abdul-Kader, M. Lopes, C. Bartual-Murgui, L. Salmon, P. Zhao, G. Molnár, D. Astruc, A. Bousseksou .

J. Nanophotonics , 2012, 6, 063517


387. Encapsulation of water-soluble vitamins in hydrophobic media.

P. Zhao, J. Ruiz, D. Astruc. Chem. Lett. 2012, 41, 1107-1109.


388 . Click Synthesis and Redox Chemistry of Mono- and Heterobimetallic Triazolyl and Triazolium-Ferrocene and Cobalticinium Complexes.

A. Rapakousiou, C. Mouche, M. Duttine, J. Ruiz, and D. Astruc. Eur. J. Inorg. Chem., 2012, 5071-5077.




362. How Do Nitriles Compare with Isoelectronic Alkynyl Groups in the Electronic Communication between Iron Centers Bridged by Phenylene-Bis- and Tris-Nitrile Ligands? An Electronic and Crystal-structure Study.

L. Bonniard, S. Kahlal, A. K. Diallo, C. Ornelas, T. Roisnel, G. Manca, J. Rodrigues, J. Ruiz, D. Astruc, J.-Y. Saillard

Inorg. Chem . 2011, 50, 114–124


363. Olefin Metathesis in Nano-sized Systems.

D. Astruc, A. K. Diallo, S. Gatard, L. Liang, C. Ornelas, V. Martinez, D. Méry, J. Ruiz. Beilstein J. Org. Chem . 2011, 7, 94-103


364. Bianka Tchoubar (1910-1990)

D. Astruc. In European Women in Chemistry , J. Apotheker, L. Simon Sarkadi Ed., WILEY-VCH, Weinheim, 2011, pp. 191-194


365. The 2010 Nobel Prize for palladium-catalyzed cross-coupling reaction

D. Astruc. Anal Bioanal Chem 2011, 399, 1811–1814


366. Ferrocenyl Dendrimers and their Applications.

D. Astruc. New J. Chem. 2011, 35, 764–772


367. Ferrocenyl-terminated Redox Stars: Synthesis and Electrostatic Effects in Mixed-valence Stabilization.

A. K. Diallo, C. Absalon, J. Ruiz, D. Astruc. J. Am. Chem. Soc . 2011, 133, 629-641.


368. Water-soluble glycodendrimers : synthesis and stabilization of catalytically active Pd and Pt nanoparticles.

S. Gatard, L. Liang, L. Salmon, J. Ruiz, D. Astruc, S. Bouquillon. Tetrahedron Lett . 2011, 52, 1842 - 1846


369. Redox recognition using “click” chemistry.

D. Astruc, C. Ornelas, A. Rapakousiou, L. Liang, R. Djeda, J. Ruiz. Inorg. Chim. Acta 2011, 374 (1) 51-58. (Kaim issue)


370. Organoiron mediated synthesis of functional dendrimers with 1 à 3 connectivity.

D. Astruc. J. Organomet. Chem. 2011, 696 (17) 2864-2869. (Pacichem 2010 issue)

371. From Electron-Reservoir Complexes to Dendritic Molecular Nanobatteries.

D. Astruc. Chem. Asian J. 2011, 6 (7) 16791687.


372. Detection of cholesterol by digitonin conjugated gold nanoparticles.

V. Raj, J. Ruiz, D. Astruc, K. Sreenisan. Biosens. Bioelectron. 2011, 27, 197-200.


373. “Click” assembly of carborane-appended polymers and stabilization of gold and palladium nanoparticles.

L. Liang, A. Rapakousiou, L. Salmon, J. Ruiz, D. Astruc, B. P. Dash, R. Satapathy, N. S. Hosmane. Eur. J. Inorg. Chem. 2011(20) 3043-3049.


374. Encapsulation of docetaxel into PEGylated gold nanoparticles for vectorization to cancer cells and in vitro results.

A. François, A. Laroche, N. Pinaud, L. Salmon, J. Ruiz, J. Robert, D. Astruc. ChemMedChem 2011, 6, 2003-2008.


375. The Copper(I)-catalyzed Alkyne-Azide Cycloaddition (CuAAC) “Click” Reaction and its Applications. An Overview.

L. Liang, D. Astruc. Coord. Chem. Rev. 2011, 255, 2933-2945.


376. The Efficient Copper(I)(hexabenzyltren) Catalyst and Dendritic Analogues for Green “Click” Reactions between Azides and Alkynes in Organic Solvent and in Water. Positive Dendritic Effects and Monometallic Mechanism.

L. Liang, J. Ruiz, D. Astruc. Adv. Syn. Catal. 2011, 353, 3434-3450.




347. Encapsulation and Stabilization of Gold Nanoparticles with “Click” Polyethyleneglycol Dendrimers.

E. Boisselier, A. K. Diallo, L. Salmon, C. Ornelas, J. Ruiz, D. Astruc. J. Am. Chem. Soc. 2010, 132 , 2729–2742.


348. Dendrimers Designed for Functions: From Physical, Photophysical and Supramolecular Properties to Applications in Sensing, Catalysis, Molecular Electronics, Photonics and Nanomedicine.

D. Astruc, E. Boisselier, C. Ornelas. Chem. Rev. 2010, 110, (4), 1857–1959


349. A New, Simple Synthetic Route to Functional Mono- and Biferrocenes

K. Diallo, J. Ruiz, D. Astruc. Inorg. Chem . 2010, 49, 1913-1920.


350. Organoiron-mediated dendrimer syntheses with 1 à 3 connectivity and applications

D. Astruc, J. Ruiz. Tetrahedron Report N° 903, Tetrahedron, 2010, 66, 1769-1785.


351. Encapsulation of Vitamins C, B3 and B6 by Dendrimers in Water

E. Boisselier, L. Liang, M. Dalko-Csiba, J. Ruiz, D. Astruc. Chem. Eur. J . 2010, 16, 6056-6068.


352. Palladium Catalysis Using Dendrimers: Molecular Catalysts versus Nanoparticles

D. Astruc. Tetrahedron Asymmetry 2010, 21, 1041-1054. (dedicated to Henri Kagan in Henri Kagan’80th birthday issue)


353. Click” Synthesis of Organosilicon Dendrimers

D. Astruc, C. Ornelas, J. Ruiz. Main Group Chemistry, 2010, 9, 87-100 (special Alan Cowley issue).


354. Branching the Electron-Reservoir Complex [Fe( h 5 -C 5H 5)( h 6 -C 6Me 6)][PF 6] onto Large Dendrimers : “Click”, Amide and Ionic Bonds.

R. Djeda, C. Ornelas, J. Ruiz, D. Astruc. Inorg. Chem . 2010, 49 (13), 6085–6101

355. Activation of Mesitylene Involving Multiple Carbon-Carbon Bond Formation under Ambient Conditions with Regeneration of the Organoiron Group.

A. C. Sandler, J. Ruiz, D. Astruc.Organometallics 2010, 29, 5722–5724


356. Extremely Efficient Catalysis of Carbon-Carbon Bond Formation Using "Click" Dendrimer-Stabilized Palladium Nanoparticles.

D. Astruc, C. Ornelas, A. K. Diallo, J. Ruiz. Molecules , 2010, 15, 4947-4960.


357. “Click” synthesis of an heterobifunctional ferrocenyl dendrimer with molecular recognition properties and influence of the ferrocenyl redox potential on the formation of gold nanoparticles.

L. Liang, J. Ruiz, D. Astruc. J. Inorg. Organomet. Polym. Mater . 2010, 20 (3), 503-510.


358. Water soluble metallocenes: “click” synthesis of ferrocenyl- and cobaltocenyltriazolyl- b -cyclodextrins and catalytic properties.

A. K. Diallo, S. Menuel, E. Monflier, J. Ruiz, D. Astruc. Tetrahedron Lett . 2010, 51, 4617-4619.


359. Dendrimer-induced Molecular Catalysis in Water: the Example of Olefin Metathesis.

A. K. Diallo, E. Boisselier, L. Liang, J. Ruiz, D. Astruc. Chem. Eur. J . 2010, 16, 11832 – 11835


360. "Click Syntheses of Large 1,2,3-TriazolylbiFerrocenyl Dendrimers and Selective Roles of the Inner and Outer Ferrocenyl Groups in the Redox Recognition of  the ATP2- Anion and PdII Cation".

R. Djeda, A. Rapakousiou, L. Liang, N. Guidolin, J. Ruiz, D. Astruc. Angew. Chem., Int. Ed . 2010, 49, 8152-8156


361. “Click” Synthesis and Properties of Carborane-Appended Large Dendrimers

R. Djeda, J. Ruiz, D. Astruc, R. Satapathy, B. Prasanna Dash, N. S. Hosmane. Inorg. Chem . 2010, 49, 10702-10709.




327. Giant Dendritic Molecular Electrochrome Batteries with Ferrocenyl and Pentamethylferrocenyl Termini.

C. Ornelas, J. Ruiz, C. Belin, D. Astruc. J. Am. Chem. Soc ., 2009, 131, 590-601.


328. New polyalkynyl dendrons and dendrimers, click chemistry with azidomethylferrocene and anion and cation redox sensing properties of the 1,2,3-triazole-containing dendrimers.

J. Camponovo, J. Ruiz, E. Cloutet, D. Astruc. Chemistry, Eur. J ., 2009, 15 , 2990-3002.


329. Ferrocenyl Dendronized Polymers

E. Boisselier, A. Chan Kam Shun, J. Ruiz, Eric Cloutet, C. Belin, D. Astruc. New J. Chem . 2009, 33, 246–253 (special Jean-Pierre Sauvage issue)


330. Visible-light Photolysis of [FeCp( h 6 -toluene)][PF 6] as a Clean, Convenient and General Route to Iron-vinylidene and Iron-acetylide Complexes"

C. Ornelas, J. Ruiz, D. Astruc, J. Organometal. Chem . 2009, 694, 1219-1222 (Special Chris Elschenbroich issue).


331. How do redox groups behave around a rigid molecular platform Hexa(ferrocenylethynyl)benzenes and their “electrostatic” redox chemistry

A. K. Diallo, J.-C. Daran, F. Varret, J. Ruiz, D. Astruc. Angew. Chem., Int. Ed . , HIP 2009, 48, 3141-3145.


332. Gold Nanoparticles in Nanomedicine : Peparations, Diagnostic, Therapy and Toxicity

E. Boisselier, D. Astruc. Chem. Soc. Rev ,. 2009, , 38, 1759–1782 (special Jean-Pierre Sauvage issue).


333. Dendrimer Construction : (CpFe) +-induced Formation of the Polyallyl Arene Core and Dendron, and Iteration Using Hydrosilylation and Williamson Reactions.

C. Ornelas, R. Djeda, J. Ruiz, D. Astruc. In Experiments in Green and Sustainable Chemistry (Eds. : H. Roesky, T. Kennenpohl), Wiley, Weinheim, 2009, Ch. 40, pp 245-255.


334. Ferrocenyl-1,2-3-Triazolyl Dendrimers by “Click” Chemistry..

C. Ornelas, J. Ruiz, D. Astruc. In Experiments in Green and Sustainable Chemistry (Eds. : H. Roesky, T. Kennenpohl), Wiley, 2009, Chap. 27, pp. 178-183.


335. Electronic Communication between Immobilized Ferrocenyl Dendrimers "

Wang, Aifang; Ornelas, Catia; Astruc, Didier; Hapiot, Philippe. J. Am. Chem. Soc . 2009, 131 , 6652–6653.


336. Giant cobalticinium dendrimers.

C. Ornelas, J. Ruiz, D. Astruc. Organometallics , 2009 , 28 (9), 2716-2723.


337. Electron Reservoirs and other redox-robust complexes

D. Astruc. New J. Chem. 2009 , 33 , 1191–1206 (special issue on Molecular Materials).


338. "Click” Glycodendrimers Containing 27, 81 and 243 Modified Xylopyranoside Termini

J. Camponovo, C. Hadad, J. Ruiz, E. Cloutet, S. Gatard, J. Muzart, S. Bouquillon, D. Astruc. J. Org. Chem . 2009, 74, 5171-5074.


339. A New, Facile and General Synthesis of Functional and Heterodifunctional Ferrocenes

A. Diallo, J. Ruiz, D. Astruc. Org. Letters 2009, 11 (12) 2635-2637.


340. Metallocenyl Dendrimers as Electrochrome Molecular Batteries

D. Astruc, C. Ornelas, J. Ruiz. Chemistry, Eur. J . ( Concept Article) 2009, 15, 8936-8944


340. Dendrimers containing redox-robust metallocenes

D. Astruc, C. Ornelas, J. Ruiz, C. Belin. Polym. Preprint, A.C. S., Washington, soumis le 15 mars, accepté le même jour.


341. Dendritic and Ion-Pairing Effects in Oxo-anion Recognition by Giant Alkylferrocenyl Dendrimers

C. Ornelas, J. Ruiz, D. Astruc. Organometallics 2009, 28, 4431–4437.


342. Electron-Transfer Mediation on Poly-aryl Dendrimer-modified Electrodes

A. Wang, J.-M. Nöel, D. Zigah, C. Ornelas, C. Lagrost, D. Astruc, P. Hapiot. Electrochem. Commun . 2009, 11, 1703-1706.


343. “Click” polymer-supported palladium nanoparticles as highly efficient catalysts for olefin hydrogenation and Suzuki coupling reaction under ambient conditions.

C. Ornelas, A. K. Diallo, J. Ruiz, D. Astruc. Adv. Synth. Catal 2009, 351 , 2147 – 2154.


344. Dendritic Molecular Electrochrome Batteries based on Redox-Robust Metallocenes

D. Astruc, C. Ornelas, J. Ruiz. Chem. Eur. J. 2009, 15, 8936-8944.


345. Towards molecular batteries: coverage of small amino-silica nanoparticles with ferrocenyl and pentamethylferrocenyl groups and their redox properties .

T. Kusamoto , J. Ruiz, D. Astruc. New J. Chem. 2009, 33, 2204-2209.




311. "Click” Dendrimers: Synthesis, Redox Sensing of Pd(OAc) 2, and Remarkable Catalytic Hydrogenation Activity of Precise Pd Nanoparticles Stabilized by 1,2,3-Triazole-Containing Dendrimers".

Ornelas, L. Salmon, J. Ruiz Aranzaes, D. Astruc. Chem. Eur. J., 2008 , 14 (1) 50-64.


312. Simple synthesis of organo-iron complexes from iron-sandwich raw materials using visible light.

J. Ruiz Aranzaes, D. Astruc. Inorg. Chim. Acta, 2008, 361 (1) 1-4.


313. Ferrocenyl-teminated Dendrimers : Design for Applications in Molecular Electronics, Molecular Recognition and Catalysis

D. Astruc, C. Ornelas, J. Ruiz Aranzaes. J. Inorg. Organomet. Polym. Mater., 2008 , 18 (1) 1-4.


314. A highly active and reusable copper(I)-tren catalyst for the click 1,3-dipolar cycloaddition of azides and alkynes.

N. Candelon, D. Lastécouères, A. K. Diallo, J. Ruiz Aranzaes, D. Astruc, J.-M. Vincent. Chem. Commun . , 2008, 741-743.


315. Cross Olefin Metathesis for the Selective Functionalization, Ferrocenylation, and Solubilization in Water of Olefin-terminated Dendrimers, Polymers and GoldNanoparticles and for a Divergent Dendrimer Construction

C. Ornelas, D. Méry, E. Cloutet, J. Ruiz Aranzaes, D. Astruc. J. Am. Chem. Soc. 2008, 130, 1495-1506.


316. Correlation between Functiolnal Density and Experimental Studies of Three New 1-Electron Metal Sandwich Complexes ContainingAmido, Ester and Thioester Cyclopentadienyl Substituents

S. Kahlal, C. Ornelas, J. Ruiz Aranzaes, D. Astruc, J.-Y. Saillard. Organometallics , 2008, 27 (15) 3603-3700.


317. Sulfonated “Click” Dendrimer-Stabilized Palladium Nanoparticles as Highly Efficient Catalysts for Olefin Hydrogenation and Suzuki Coupling Reactions Under Ambient Conditions in Aqueous Media

C. Ornelas, J. Ruiz, L. Salmon, D. Astruc. Adv. Syn. Catal., 2008, 350 (6), 837-845.


318. Four Generations of Water Soluble Dendrimers with 9 to 243 Benzoate Tethers : Synthesis and Dendritic Effects on Their Ion Paring with Acetylcholine, Benzyltriethylammonium and Dopamine in Water

E. Boisselier, C. Ornelas, I. Pianet, J. Ruiz, D. Astruc. Chemistry, Eur. J., 2008, 14 , 5577-5587


319. Visible-light Photolytic Synthesis of Multinuclear and Dendritic Iron-nitrile Cationic Complexes

C. Ornelas, J. Ruiz, J. Rodrigues, D. Astruc. Inorg. Chem. , 2008, 47 , 4421-4428.


320. Synthesis and Coordination Chemistry of Ferrocenyl-1,2,3-triazolyl Ligands

S. Badèche, J.-C. Daran, J. Ruiz, D. Astruc,. Inorg. Chem ., 2008, 47, 4903-4908.




296 Click Assembly of 1,2,3-Triazole-Linked Dendrimers Including Ferrocenyl Dendrimers that Sense Both Oxo-anions and Metal Cations **

C. Ornelas, J. Ruiz Aranzaes, E. Cloutet, S. Alves, D. Astruc. Angew. Chem. Int. Ed., 2007 , 46 (1 ) 872-877.


297 Palladium Nanoparticles as Efficient Green Homogeneous and Heterogeneous Carbon-Carbon Coupling Pre-catalysts: A Unifying View

D. Astruc. Inorg. Chem., 2007, 46 (6), 1884-1894.


298 Peripheral functionalization of dendrimers with polyoxotunsgtate complexes assembled by ionic bonding and their use as oxidation catalysts: Influence of the tether length.

S. Nlate, L. Plault, D. Astruc. New J. Chem. 2007, 31(7), 1264-1274.


299 Transition-Metal Nanoparticles in Catalysis: From Historical Background to the State-of-the Art

D. Astruc. In Nanoparticle and Catalysis (Forword and Chapter 1, pp. 1-48), D. Astruc Ed., Wiley-VCH, Weinhein, 2007.


300 Organometallic Chemistry and Catalysis

D. Astruc, Textbook with 21 chapters, corrected exercises and 500 selected references, 608 pp. Springer, Berlin, 2007.


301 Organometallic Electron Reservoir Complexes. Concepts and Applications

D. Astruc, Bull. Soc. Chim. Jpn , 2007, 80, 1658-1671.


302 The Olefin Metathesis Reactions in Dendrimers

D. Astruc , Oil & Gas Science and Technology - l'IFP review (Y. Chauvin issue), 2007, 62 (6) 787-797.


303. Assembly Between Gold-thiolate Nanoparticles and the Organometallic Cluster [Fe( h 5 -C 5H 5)( m 3 -CO)] 4 Toward Redox Sensing of Oxo-anions.

J. Ruiz Aranzaes, C. Belin, D. Astruc. Chem. Commun . 2007, 3456 -3458


304. Olefin Metathesis Reactions Combined with Organo-iron Arene Activation towards Dendrimers and Polymers .

D. Astruc, V. Martinez. In Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials . Y. Imamoglu, V. Dragutan Eds., Springer, 2007, pp. 223-236.


305. Efficient and Recyclable Dendritic Buchwald-type Catalyst for the Suzuki Reaction

J. Lemo, K. Heuze, D. Astruc. Chem. Commun. 2007 , 4351-4353


306. Catalytically Efficient Palladium Nanoparticles Stabilized by Click Ferrocenyl Dendrimers.

C. Ornelas, L. Salmon, J. Ruiz Aranzaes, D . Astruc. Chem. Commun. 2007, 4946-4948


307. Homeopathic Catalytic Activity and Atom-Leaching Mechanism in the Miyaura-Suzuki Reactions under Ambient Conditions Using Precise “Click” Dendrimer-Stabilized Pd Nanoparticles.

A. K . Diallo, C. Ornelas, L. Salmon, J. Ruiz Aranzaes, D. Astruc. Angew. Chem. Int. Ed. Engl. 2007 , 46, 8644-8648.


308. New Water-soluble Polyanionic Dendrimers and Binding to Acetylcholin in Water By Means of Supramolecular Interactions.

C. Ornelas, E. Boisselier, V. Martinez, I. Pianet, J. Ruiz Aranzaes, D. Astruc. Chem. Commun . 2007 , 5093-5095


309. Metallodendritic Iron Complexes; Design, and Molecular Recognition

D. Astruc, Frontiers in Transition Metal-Containing Polymers, A.S. Abd-El-Aziz, I. Manners, Editors, Wiley-Interscience, John Wiley and Sons, Inc., New York, 2007.




283. Assembly of Dendrimers with Redox-Active Clusters [CpFe( m 3 -CO)] 4 at the Periphery and Application to Oxo-anion and Adenosyne-5’-Triphosphate (ATP) Sensing

J. Ruiz Aranzaes, C. Belin, D. Astruc, Angew. Chem. 2006 , 118, 138-142 ; Angew. Chem. Int. Ed., 2006, 45 (1), 132-136.


284. Synthesis of Ferrocenylazobenzene-attached Dendrimers and Light-induced Redox-Activity Control of Their Modified Electrodes

M.-C. Daniel, A. Sakamoto , J. Ruiz, D. Astruc, H. Nishihara. Chem. Lett ., 2006 , 35 (1), 38-39.


285. Giant Dendrimer Construction: Hydroboration vs. Hydrosilylation as a Growth Strategy

J. Ruiz, G. Lafuente, S. Marcen, C. Ornelas, S. Lazarre, E. Cloutet, J.-C. Blais, D. Astruc, In Recent Advances in Main-Group Chemistry, M. Lattman, R. A. Kemp Eds.; ACS Sym. Series N°917, 2006, Chap. 25, pp. 347-361 (special Alan H. Cowley issue)


286. Synthesis of 9- and 27-Armed Tetrakis(diperoxotungsto)phosphate-cored Dendrimers and their Use as Recoverable and Re-usable Catalysts in the Oxidation of Alkenes, Sulfides and Alcohols with Hydrogen Peroxide

S. Nlate, L. Plault, D. Astruc. Chem. Eur. J., 2006, 12 (3), 903-914.


287 From Simple Monopyridine Clusters [Mo 6Br 13(Py-R) 6][n-Bu 4N] and Hexapyridine Clusters [Mo 6X 8(Py-R) 6][OSO 2CF 3] 4 (X = Br or I) to Cluster- cored Organometallic Stars, Dendrons and Dendrimers .

D. Méry, L. Plault, C. Ornelas, J. Ruiz, S. Nlate, D. Astruc, J.-C. Blais, J. Rodrigues, S. Cordier, K. Kiracki, C. Perrin, Inorg. Chem., 2006 , 45 (3), 1156-1167.


288. Inorganic Mo 6X 14 clusters and their functionalization

S. Cordier, K. Kirackci, C. Perrin, D. Méry, D. Astruc, Inorg. Chim. Acta , 2006, 359 (6) 1705-1709 (special Gérard van Koten issue)


289. Metallodendritic Catalysis : Major Concepts and Recent Progress

D. Méry and D. Astruc. Coord. Chem. Rev ., 2006, 250 (15-16), 1965-1979.


290. Metallocenes as references for the determination of redox potentials by cyclic voltammetry: permethylated iron and cobalt sandwich complexes, inhibition by polyamine dendrimers and the role of hydroxy-containing ferrocenes

J. Ruiz , M.-C. Daniel, D. Astruc, Can. J. Chem., 2006 , 84, 288-299 (special Arthur Carty issue)


291. Synthesis and Catalytic Activity of DAB-dendrimer encapsulated Pd nanoparticles for the Suzuki coupling reaction.

J. Lemo, K. Heuze, D. Astruc. Inorg. Chim. Acta , 2006 , 359 (15), 4909-4911 (special Wolfgang Herrmann issue).


292. Can t-BuOK be a Good Nucleophile? An Ion-Pairing Answer. Cleavage of Aryl Ethers in their Cationic Iron Complexes.

D. Astruc, L. Djakovitch, J. Ruiz Aranzaes. Arkivoc, 2006 (special Armand Lattes issue), AL-1794FP.


293. Use of an Electron-reservoir Complex together with Air to Generate N-Heterocyclic Carbenes

D. Méry, J. Ruiz Aranzaes, D. Astruc. J. Am. Chem. Soc . 2006, 128 (17), 5602-5603.


294. Metallodendritic exo-receptors for the redox recognition of oxo-anions and halides

D. Astruc, M.-C. Daniel, J. Ruiz . Topics Organometal. Chem. 2006, 20, 121-148.


295. A one-pot synthesis of a 243-allyl dendrimer under ambient conditions

C. Ornelas, J. Ruiz, D. Astruc. Org. Lett. 2006, 8 (13), 2751-2753.



271 The Metathesis Reactions: From Historical Perspective to Recent Development
D. Astruc
New .J. Chem., 2005, 29, 42-56.

272 Dendritic Phosphonates and the in situ Assembly of Polyoxophosphotungstates: Synthesis and Catalytic Epoxidation with Hydrogen Peroxide.
M. V. Vasylyev, D. Astruc, R. Neumann Adv. Synth. Catal. 2005, 347, 39-43.


273 Mo6Br8-Cluster-cored Organometallic Stars and Dendrimers
D. Méry, C. Ornelas, J. Ruiz, J. Rodriguez, D. Astruc, S. Cordier, K. Kiraki, C. Perrin. C. R. Chimie, special issue on “New molecular architectures built from metallic nanoclusters”, C. Perrin, A. Perrin, D. Fenske Eds, 2004, 8, 1789-1797.


274 La catalyse métallodendritique : une contribution efficace à la chimie verte
D. Astruc. C. R. Chimie, 2005, 8, 1101-1107, (special Francis Sécheresse issue)


275 Giant Dendrimer Construction: Hydroboration vs. Hydrosilylation as a Growth Strategy
J. Ruiz, G. Lafuente, S. Marcen, C. Ornelas, S. Lazarre, E. Cloutet, J.-C. Blais,
D. Astruc. ACS Sym. Series N°XXX, Recent Advances in Main-Group Chemistry, accepted for publication on October 15, 2004 (special issue dedicated to Alan H. Cowley)


276 Metallodendritic Catalysis for Redox and C-C Bond Formation Reactions : A Step towards Green Chemistry
D. Astruc, K. Heuze, S. Gatard, D. Méry, S. Nlate, L. Plault. Advan Syn. Catal., 2005, 347, 329-338 (special Richard R. Schrock issue)

277 Gold-nanoparticule-cored Polyferrocenyl Dendrimers: Modes of Synthesis and Functions as Exoreceptors of Biologically Important Anions and Re-usable Redox Sensors
M.- C. Daniel, J. Ruiz, S. Nlate, D. Astruc. J. Inorg. Organomet. Polym. Mat., 2005, 15 (1) 107-119


278 Inhibition of the electrochemistry of ferrocenes by polyamine dendrimers and the key role of hydrogen-bonding with hydroxy groups
M.-C. Daniel, J. Ruiz, D. Astruc
Chem. Commun. 2005, 1569-1571


279 Metallocenes as references for the determination of redox potentials by cyclic voltammetry: permethylated iron and cobalt sandwich complexes, inhibition by polyamine dendrimers and the role of hydroxy-containing ferrocenes
J. Ruiz , M.-C. Daniel, D. Astruc, Can. J. Chem., 2005 In press (special Arthur Carty issue)


280 The Simple Hexapyridine Cluster [Mo6Br8Py6][OSO2CF3]4 and Substituted Hexapyridine Clusters Including a Cluster-cored Polyolefin Dendrimer
D. Méry, L. Plault, S. Nlate, D. Astruc, S. Cordier, K. Kirackci, C. Perrin, Z. Anorg.. Allgem. Chem. 2005, 631, 2746-2750 (special Herbert Roesky issue).


281 Efficient Dendritic Diphosphino Pd(II) Catalysts for the Suzuki Reaction of Choroarenes
J. Lemo, K. Heuzé, D. Astruc. Org. Letters, 2005, 7 (11) 2253-2256.


283 Inorganic Mo6X14 clusters and their functionalization
S. Cordier, K. Kirackci, C. Perrin, D. Méry, D. Astruc, Inorg. Chim. Acta, 2005, In press (special Gérard van Koten issue).


284 Nanoparticles as Recyclable Catalysts: the Fast-growing Frontier between Homogeneous and Heterogeneous Catalysts
D. Astruc, F. Lu, J. Ruiz Aranzaes. Angew. Chem. 2005 , 117, 8062-8083; Angew. Chem. Int. Ed., 2005, 44, 7852-7872.


285 Mono-and Bifunctionalization of Polyallyl Dendrimers by Metathesis.
C. Ornelas, D. Méry, J. Ruiz, J.-C. Blais, E. Cloutet, D. Astruc. Angew. Chem. 2005 , 117, 7565-7570; Angew. Chem. Int. Ed., 2005, 44, 7399-7404



Selected Reviews : 1983-2000


Organo-Iron Complexes of Aromatic Compounds. Applications in Synthesis.
Astruc, D.
Tetrahedron Report n° 157, Tetrahedron, 1983, 39, 4027-4095.

Organometallic Electron, H-Atom, and Hydride Reservoirs : Single Electron or H-atom Transfers in the Reduction of Iron Sandwich Complexes by Hydrides or H2/Pd/C ; Reduction of Isolobal Carbonyl Complexes, a Model System for the Fisher-Tropsch Synthesis.
Michaud, P. ; Lapinte, C. ; Astruc, D.
Annals New-York Acad. Sciences, 1983, 415, 97-110.

Activation of Dioxygen and of Other Small Molecules Using Organometallic Electron-Reservoir Complexes.
Astruc, D. ; Román, E. ; Hamon, J.-R. ; Madonik, A.M. ; Desbois, M.-H. ; Guerchais, V. Michaud, P. ; Lacoste, M.
Bol. Soc. Chil. Quim., 1985, 1-15.

Organoiron Electron Reservoir Complexes.
Astruc, D.
Acc. Chem. Res., 1986, 19, 377-383.

New Entries to Organo-Iron Chemistry: The Pentamethylcyclopenta-dienyl Complexes.
Manriquez, J.M. ; Astruc, D.
Bol. Soc. Chil. Quim., 1986, 31, 161-169.

Thermally Stable 19 Electron Fe(I) and Related Complexes (Experimental).
Astruc, D. ; Hamon, J.-R. ; Lacoste, M. ; Desbois, M.-H. ; Román, E.
"Organomet. Synthesis", R.B. King Ed., Vol. IV, 1988, 172-187.

Electron-Transfer Chain Catalysis in Organo-Transtion-Metal Chemistry.
Astruc, D.
Angew. Chem. Int. Ed. Engl., 1988, 27, 643-660 ; Angew. Chem., 1988, 100, 662-680.

Nineteen-Electron Organometallic Complexes and their Role in Organometallic Mechanisms.
Astruc, D.
Chem. Rev., 1988, 88, 1189-1216.

The Role of Transition Metal-Centered Radicals in Inorganic and Organometallic Chemistry.
Román, E. ; Astruc, D.
Bol. Soc. Chil. Quim., 1989, 34, 39-58.

Aspects of Aromatic Iron Sandwichs : Application to Organic and Organometallic Synthesis.
Astruc, D. ; Hamon, J.-R. ; Mandon, D. ; Moulines, F.
Pure Appl. Chem, 1990, 62, 1165-1168.

Iron-Sandwichs as Molecular Reservoir Materials : Design, Electronic Properties and Prospects.
Astruc, D. ; Desbois, M.-H. ; Lacoste, M. ; Moulines, F.
Polyhedron, 1990, 2727-2732.

Transition Metal Radicals : Chameleon Structure and Catalytic Function.
Astruc, D.
Acc. Chem. Res., 1991, 24, 36.

Organo-Iron Complexes in Aromatic Synthesis.
Astruc, D. ; Desbois, M.-H. ; Gloaguen, B. ; Moulines F. ; Hamon, J.-R.
"Organic Synthesis via Organometallics", K.H. Dötz, R.W. Hoffmann Eds. Vieweg Braunschweig 1991, 63-75.

The Transformation of Aromatics int Regio- and Stereocontrolled Heterobifunctional Cyclohexadienes Mediated by Temporary Sandwich Complexation. Role of Electron, Proton, Hydride and Hydrogen-Atom Transfers.
Astruc, D.
Synlett, 1991, 369-380.

The Use of ?-Organoiron Sandwiches in Aromatic Chemistry.
Astruc, D.
Top. Curr. Chem., 1991, 160, 47-95.

Salt Effects Resulting from Exchange between Two Ions Pairs.
Loupy, A. ; Tchoubar, B. ; Astruc, D.
Chem. Rev., 1992, 92, 1141-1165.

Electron-Transfer-Chain Catalysis : Role of Transition-Metal Radicals, Side Reactions and Coupling with Organometallic Catalysis.
Astruc, D. ; Delville, M.-H. ; Ruiz, J.
In "Molecular Electochemistry of Inorganic, Bioinorganic and Organometallic Compounds", Pombeiro, A.J. L. ; Mc Cleverty, J.M. Eds., NA ASISeries, Vol 385, Kluwer, Dordrecht, pp 277-294.

The Magic Salt Effects of Sodium Hexafluorophosphate
Astruc, D. ; Delville-Desbois, M.-H. ; Lacoste, M. ; Ruiz, J. ; Moulines, F. ; Hamon, J.-R.
dans "Recent Advances in the Chemistry of the Main-Group Elements" Hosmane, N. Ed., Phosphorus, Sulfur, Silicon and the Related Elements, 1994, 87, 11-22.

The Molecular Trees : from Syntheses towards Applications.
Ardoin, N. ; Astruc, D.
Bull. Soc. Chim. Fr. 1995, 132, 875-909

Homogeneous Electrocatalysis
Astruc, D. “Applied Homogeneous Catalysis with Organometallic Compounds” Cornils, B. ; Herrmann, W.A. Eds., VCH, Weinheim, 1996, Chapitre 3.2.8.

Electron-Reservoir Sandwich Complexes : From Mono- and Bimetallic Complexes to Molecular Trees
Astruc, D. ; Valério, C. ; Fillaut, J.-L. ; Ruiz, J. ; Hamon, J.-R. ; Varret, F.
“Supramolecular Magnetism” Kahn, O. Ed. NATO ASAI Séries, Kluwer, Dordrecht, 1996, 107-127.

Research Avenues on Dendrimers Towards Molecular Biology :
from Biomimetism to Medicinal Engineering
Astruc, D.
C. R. Acad. Sci. 1996, 322, Série II b, 757-766.

Transferts d’Electrons à l’aide de Molécules Réservoirs : Matériaux, Activation et Catalyse
Astruc, D.
L’Actualité Chimique 1996, 7, 69-74.

From Organotransition-Metal Chemistry toward Molecular Electronics : Electronic Communication between ligand- Bridged Metals
Astruc, D.
Acc. Chem. Res. 1997, 30, 383-391

Organo-Transition Metal Dendrimers.
Valério, C. ; Alonso, E. ; Ruiz, J. ; Fillaut, J.-L. ; Moulines, F. ; Astruc, D.
in “Selective Reactions of Metal-Activated Molecules” H. Werner, P. Schreier Eds, Vieweg, Braunschweig, 1998, pp 207-215.

Redox-Active Organo-Transition Metal Dendrimers: The Dendritic Effect in Supramolecular Recognition.
Guittard, J.; Blais, J.-C.; Valério, C.; Alonso, E.; Ruiz, J.; Fillaut, J.-L.; Astruc, D.
Pure Appl. Chem 1998, 70, n° 4, 809-814.

Engineering Nanoscopic Macromolecules for Applications: Stars versus Dendrimers for Catalysis and Sensoring.
Valério, C. ; Rigaut, S. ; Ruiz, J. ; Fillaut, J.-L. ; Delville, M.-H. ; Astruc, D.
Bull. Pol. Acad.Sc., 1998,.46, 309-318.

Electron-Reservoir Fe(I) Complexes: Multiple Applications for Electron-Transfer Processes and the Extraordinary Reactivity of Superoxide Anion Generated from Dioxygen and Fe(I).
Astruc, D. ; Rigaut, S. ; Alonso, E. ; Delville, M.-H. ; Ruiz, J. Hung. Chim. Acta., 1998, 135, 751-769




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